Just crashed while selecting the British fleet in the Caribbean after starting the Thames or Danube scenario and doing my initial organization.
Log and campaign save enclosed. Though I'm not sure if there's anything in the campaign files as I hadn't even ended a turn yet.
Note: I just reinstalled a fresh copy of this and put the latest 1.07 update in (the one that says release candidate 1 on the load screen). I also installed to a regular folder (C:/Games/##) instead of /Program Files (x64) on my Windows 7, along with checking Run As Admin and Disable Desktop Composition. UAC is disabled.